Atomic Absorption Spectroscopy (AAS) usually refers to a known metal ion with unknown concentration.
To determine concentration of a certain metal ion, you need samples of standard solutions of known concentration to make a calibration curve - graphing absorbance against concentration. Once a calibration curve is made, you can also determine the concentration based on the extent to which specific wavelength of light is absorbed (characteristic of the metal ion tested), comparing it to the calibration curve and hence, determine an approximate concentration of a specific metal ion being tested.
Another technique called Atomic Emission Spectroscopy (AES) is used to determine the metal ions present but this is not in the core syllabus - only in the Forensic Chemistry option.