Like khorne said, just see if the ion (generally is one) can both accept AND donate a proton. Quite obviously a neutral acid molecule of acetic acid will not be amphiprotic. It can only donate a proton and not accept it. Similarly, an acetate ion can only accept a hydronium ion and not donate one. A polyprotic acid (generally) forms amphiprotic ions after it's first complete ionisation. Look a simple indication for the HSC level is to notice a charge and the presence of H. Eg. HCO3-, H2PO4-, HPO4- etc.
A noted exception is H2O which is amphiprotic despite an evident lack of charge.