Just wrong word BlueGas, it's amphiprotic.
@OP: In water, NaHCO3 does behave as a base. But consider the following equations:
Proton donor: NaHCO3 + NaOH -> Na2CO3 + H2O
Proton acceptor: NaHCO3 + HCl -> CO2 + H2O + NaCl
Clearly, the substance can behave as a Bronsted-Lowry acid, or base. Hence it is amphiprotic.