I'm not sure if I can explain this but I'll give it a shot.
Chromium and Nickel alloys are used in steel as they form an insoluble oxide layer over the steel, this prevents rusting/corrosion from occuring. Carbon is also used in steel to reinforce it, e.g. structural steel, when there is a large percent of carbon in the steel (>2%), the carbon can begin to corrode, this carbon will then allow a site for reduction/oxidation to take place.
Mild steel and structural steel have a larger percentage of carbon in them and no galvanic components.